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When did China Grottoes begin to use some plant blue dyes?
This practice was in the Song Dynasty.

In the Song Dynasty, some cave murals and sculptures began to use plant-based blue dyes, showing a more vivid blue effect.

Plant blue dye is usually extracted from roots, stems, leaves and other parts of plants, which has certain environmental protection and naturalness. Compared with traditional mineral dyes, it has better stability and durability, and can better preserve and present the colors and details of artistic works.