In some cases, the national football team may be related to business operations. In this case, the football team emblem may be registered as a trademark and used in some commercial occasions. As long as the team logo is registered as a trademark, it will be protected by the trademark law, but it is ok to use it for non-profit purposes in ordinary non-commercial occasions.
To sum up: there is nothing wrong with printing the national emblem on football, and printing the team emblem needs to examine the copyright status of each symbol. Of course, in practice, it is nobody's business for a small enterprise to produce tens of thousands of footballs.