Formula of ferric chloride corroding stainless steel: ferric chloride, activator and water. The Baume degree of ferric chloride in the formula should be kept at about 42, and 0.8- 1.2 ml of active agent should be added to every liter of ferric chloride solution. The bottom surface of stainless steel corroded by this formula is smooth and flat, without black passivation film and pitting.
The factors affecting the corrosion of stainless steel by ferric chloride solution are as follows:
A. the influence of concentration. Chemical corrosion is also called microbattery corrosion. The more positive the redox potential, the faster the corrosion rate. With the increase of concentration, the redox potential becomes positive and the corrosion rate increases. Industrial grade ferric chloride has low purity and negative redox potential. When Baume degree is above 42, the redox potential can meet the requirements of stainless steel corrosion.
B. Effect of PH value of solution on corrosion rate. Low PH value is corrosive to stainless steel; When the PH value is too high, ferric trichloride is hydrolyzed into ferric hydroxide precipitate, which loses its corrosive effect. When corrosive liquid is used to a certain extent in production, the PH value should be adjusted.
C. influence of corrosive liquid temperature. The higher the temperature of corrosive liquid, the faster the corrosion rate. However, considering the bearing capacity of corrosion-resistant ink, the temperature should be controlled between 30-40℃.